During electrophilic aromatic substitution, a resonance-stabilized cation intermediate is formed. Groups, already present on the benzene ring, that direct ortho/para further stabilize this intermediate by participating in the resonance delocalization of the positive charge. Assume that the following group is present on a benzene ring at position 1 and that you are brominating the ring at positon 4. Draw the structure of the resonance contributor that shows this group actively participating in the charge delocalization.
-----OCH3
Answers
Answer:
See explanation and image attached
Explanation:
Aromatic compounds undergo electrophilic aromatic substitution reactions in which the aromatic ring is maintained.
Substituted benzenes may be more or less reactive towards electrophilic aromatic substitution than benzene depending on the nature of the substituent present in the ring.
Substituents that activate the ring towards electrophilic substitution such as -OCH3 are ortho-para directing.
The major products of the bromination of anisole are p-bromoanisole and o-bromoanisole. The resonance structures leading to these products are shown in the image attached.
Related Questions
What mass of precipitate (in g) is formed when 250.0 mL of 0.150 M CuCl₂ is mixed with excess KOH in the following chemical reaction?
CuCl₂(aq) + 2 KOH(aq) → Cu(OH)₂(s) + 2 KCl(aq)
Answers
Answer:
3.6487g
CuCl2 moles reacted = (0.15×250)/1000
according to balanced chemical equation
precipitated Cu(OH)2 moles = Reacted CuCl2 moles
molar mass of Cu(OH)2 = 63.5+ (17+1)×2 = 97.5
mass of precipitate = (97.5 × 0.15×250)/1000
= 3.648g
how is the akin of frog similar to a fish
Answers
Answer:
Have you ever touched a fish? Most fish will feel a bit rough - due to their scales. Some, like sharks, will feel like sandpaper. Even fish with small, smoother scales will feel a bit like that. Amphibians don’t have scales, and most species will be wet to some degree - they have to keep their skin moist or they’ll die. A few groups, like toads and newts, have rougher skin, which is heavier and thicker, which allows them to retain moisture better away from water.
Functionally, the big thing about amphibian skin is that it is semi-permeable. Amphibians can breathe through their skin - all amphibians can get some oxygen through their skin, but some species of salamanders get all their oxygen that way - they have no lungs or gills. The skin can also allow water in - sort of like a paper towel. The bad thing is that other chemicals can pass through the skin, too - pollutants and other chemicals tend to affect amphibians far more than they do other groups.
Amphibians also shed their skin - fish do not. People don’t tend to see frogs shedding their skin often, though, since they eat it to regain nutrients and other resources in the skin.
Finally, since amphibian skin offers no defense against predators in the way that scales do, and limited barrier against disease the way non-amphibian skin does (shedding helps), the skin of many amphibians contain toxins, and some of them have anti-fungal properties (typically due to symbiotic bacteria). Many species have evolved chemical defenses in the skin, while others have glands that produce toxins that can be secreted outside of the skin.
The skin can withstand dessication more than the fish.
They have moist skin used as respiratory surface during deep sleep / hibernation.
They have moist skin due to secretion of mucus by glands under the skin.
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Determine whether each of the examples represents a colligative property or a non-colligative property. boiling point elevation Choose... color Choose... freezing point depression Choose... vapor pressure lowering Choose... density Choose...
Answers
Answer:
boiling point elevation - colligative property
color - non-colligative property
freezing point depression - colligative property
vapor pressure lowering - colligative property
density - non-colligative property
Explanation:
A colligative property is a property that depends on the number of particles present in the system.
Freezing point depression, boiling point elevation and vapour pressure lowering are all colligative properties of solutions.
Colour and density do not depend on the number of particles present hence they are not colligative properties.
The boiling point elevation, freezing point depression, and vapor pressure lowering are colligative properties. And color and density are non-colligative properties.
Explanation:
The colligative properties are the properties depending upon the number of particles of solute not on the nature of the solute.Example of colligative properties:Vapor pressure loweringElevation boiling pointDepression in freezing pointOsmotic pressureThe non-colligative properties are the properties depending upon the nature of solute and solvent.Example of non-colligative properties :ViscositySurface tensionDensitySolubilitySo, from this, we can conclude that boiling point elevation, freezing point depression, and vapor pressure lowering are colligative properties. And color and density are non-colligative properties.
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The sample concentration was measured at 50mg/ml. The loading concentration needs to be 10mg/ml. The final volume needs to be 25ul. What is the volume of sample needed and the amount of buffer needed to reach 25ul
Answers
Answer:
a) [tex]V_1=5ul[/tex]
b) [tex]v=20ul[/tex]
Explanation:
From the question we are told that:
initial Concentration [tex]C_1=50mg/ml[/tex]
Final Concentration [tex]C_2=10mg/ml[/tex]
Final volume needs [tex]V_2 =25ul[/tex]
Generally the equation for Volume is mathematically given by
[tex]C_1V_1=C_2V_2[/tex]
[tex]V_1=\frac{C_1V_1}{C_2}[/tex]
[tex]V_1=\frac{10*25}{50}[/tex]
[tex]V_1=5ul[/tex]
Therefore
The volume of buffer needed is
[tex]v=V_2-V_1\\\\v=25-5[/tex]
[tex]v=20ul[/tex]
lution: What is the molarity of 245 g of H, SO4 dissolved in 1.00 L of solution?
Answers
Answer:
Cm = n/V
n(H2SO4) = 245/98 = 2.5 mol
Cm(H2SO4) = 2.5/1 = 2.5 M
Explanation:
Given its formula and Avogadro's Number (6.02 x 10^23 molecules/mol), deduce how many molecules are present in 3 x 10^-16 grams of TCDD. Type in only a number without using scientific notation.
Answers
Answer:
5 × 10⁵ molecules (500,000 molecules)
Explanation:
Step 1: Convert 3 × 10⁻¹⁶ g to moles
We will use the molar mass of TCDD (321.97 g/mol).
3 × 10⁻¹⁶ g × 1 mol/321.97 g = 9 × 10⁻¹⁹ mol
Step 2: Convert 9 × 10⁻¹⁹ mol to molecules
The required conversion factor is Avogadro's number (6.02 × 10²³ molecules/mol).
9 × 10⁻¹⁹ mol × 6.02 × 10²³ molecules/1 mol = 5 × 10⁵ molecules
What Volume of silver metal will weigh exactly 2500.0g. The density of silver
Answers
Answer:
cm3 = 2500.0 g / 10.5 g/cm3 = 238 cm3
By process of incineration, a mystery substance is empirically determined to contain 40.00% carbon by weight, 6.67% hydrogen, and 53.33% oxygen. Its molecular weight ranges between 55 and 62 g/mole. a. (6 points) Determine the chemical formula of this substance
Answers
Answer:
C₂H₄O₂
Explanation:
Step 1: Divide each percentage by the atomic mass of the element
C: 40.00/12.01 = 3.331
H: 6.67/1.01 = 6.60
O: 53.33/16.00 = 3.333
Step 2: Divide all the numbers by the smallest one
C: 3.331/3.331 = 1
H: 6.60/3.331 ≈ 2
O: 3.333/3.331 ≈ 1
The empirical formula is CH₂O, with a molecular weight of 12 g/mol + 2 × 1 g/mol + 16 g/mol = 30 g/mol. The molecular weight of the compound must be a product of 30, such as 60 (between 55 and 62 g/mol). Since we have to multiply by 2 (30 to 60) to get to the molecular weight of the compound, we also have to multiply the empirical formula by 2 to get the chemical formula of the compound.
CH₂O × 2 = C₂H₄O₂
When the equation,
O2 + __C 10H 22 →
CO2 +
H2O is balanced, the coefficient of O2 is?
Please help!
Answers
This is the correct balanced equation
The coefficient would be (20) when you multiply 10 by 2
Give four examples illustrating each of the following terms. a. homogeneous mixture b. heterogeneous mixture c. compound e. physical change d. element f. chemical change
Answers
1. homogenous: sugar solution
2. heterogeneous: sand solution
3. compound: water
4. physical change: ice melting
5. element: hydrogen
6. chemical change: burning fire
20. An oxide of osmium (symbol Os) is a pale yellow solid. If 2.89 g of the compound contains 2.16 g of osmium, what is its empirical formula?
Answers
The empirical formula is OsO₄ :
Explanation:
Osmium oxide contains osmium and oxygen only.
Thus, we shall determine the mass of oxygen in osmium oxide. This can be obtained as follow:
Mass of compound = 2.89 g
Mass of Os = 2.16 g
Mass of O =?Mass of O = (Mass of compound) – (Mass of Os)
Mass of O = 2.89 – 2.16
Mass of O = 0.73 g
Finally, we shall determine the empirical formula of the compound. This can be obtained as follow:
Mass of Os = 2.16 g
Mass of O = 0.73 g
Empirical formula =..?Os = 2.16 g
O = 0.73 g
Divide by their molar mass of
Os = 2.16 / 190 = 0.011
O = 0.73 / 16 = 0.046
Divide by the smallest
Os = 0.011 / 0.011 = 1
O = 0.046 / 0.011 = 4
Empirical formula = OsO₄Learn more: https://brainly.com/question/23629778
Analyze the transition of a photon
Answers
The photon itself does not undergo a transition of energy: it either exists (with an energy defined by its wavelength), or it doesn't exist (it was destroyed!). You could say that the emitting or absorbing atom/molecule/etc. undergoes a change, or transition, in energy. But "transition" is usually used as a name for the process of jumping in energy.
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A certain atom has an energy state 3.50 eV above the ground state. When excited to this state, the atom remains for 2.0 ms, on average, before it emits a photon and returns to the ground state. (a) What are the energy and wavelength of the photon
Answers
Answer:
[tex]\lambda=3451*10^{10}m[/tex]
Explanation:
From the question we are told that:
Energy state [tex]e=3.50 eV[/tex]
Time [tex]t=2ms[/tex]
Generally the equation for energy of Photon is mathematically given by
[tex]E=e-e_0[/tex]
[tex]E=3.6*10^{-19}J[/tex]
[tex]E=5.7*10^{-19}J[/tex]
Generally the equation for Wave-length of Photon is mathematically given by
[tex]\lambda=\frac{hc}{E}[/tex]
[tex]\lambda=\frac{6.626*10^{-34}*3*10^8}{5.76*10^{-19}}[/tex]
[tex]\lambda=3451*10^{10}m[/tex]
Which statement describes the 3d, 4s, and 4p orbitals of Arsenic (As) based on its electronic configuration and position in the periodic table?
The 3d and 4s orbitals are completely filled, and the 4p orbital is partially filled.
The 3d orbital is completely filled, and the 4s and 4p orbitals are partially filled.
The 3d, 4s, and 4p orbitals are completely filled.
The 3d, 4s, and 4p orbitals are partially filled.
Answers
Answer:
The 3d and 4s orbitals are completely filled, and the 4p orbital is partially filled.
Explanation:
The correct answer is: The 3d and 4s orbitals are completely filled, and the 4p orbital is partially filled.
The d orbital contains 10 electrons, the s orbital takes 2 electrons and the p orbital takes six electrons.
The orbital in chemistry is defined as a region in space where there is a high probability of finding an electron. There are s, p, d, f orbitals in chemistry which correspond to sharp, principal, diffuse and fundamental.
The electronic configuration of arsenic is 1s2 2s2 2p6 3s2 3p6 4s2 3d10 4p3.
From this electronic configuration, we can see that the 4s and 3d orbitals are half filled while the 4p orbital is half filled.
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Given the standard enthalpy changes for the following two reactions: (1) 2Fe(s) + O2(g)2FeO(s)...... ΔH° = -544.0 kJ (2) 2Zn(s) + O2(g)2ZnO(s)......ΔH° = -696.6 kJ what is the standard enthalpy change for the reaction:
Answers
Answer:
-76.3 kJ
Explanation:
Here is the complete question
Given the standard enthalpy changes for the following two reactions:
(1) 2Fe(s) + O₂(g) → 2FeO(s)......ΔH° = -544.0 kJ
(2) 2Zn(s) + O₂(g) → 2ZnO(s)......ΔH° = -696.6 kJ. What is the standard enthalpy change for the reaction:
(3) FeO(s) + Zn(s) → Fe(s) + ZnO(s)......ΔH° = ?
Solution
Since (1) 2Fe(s) + O₂(g) → 2FeO(s)......ΔH° = -544.0 kJ
reversing the reaction, we have
2FeO(s) → 2Fe(s) + O₂(g) ......ΔH° = +544.0 kJ (4)
Adding reactions (2) and (3), we have
2FeO(s) → 2Fe(s) + O₂(g) ......ΔH° = +544.0 kJ (4)
2Zn(s) + O₂(g) → 2ZnO(s)......ΔH° = -696.6 kJ (2)
This gives
2FeO(s) + 2Zn(s) → 2Fe(s) + 2ZnO(s)......ΔH° =
The enthalpy change for this reaction is the sum of enthalpy changes for reaction (2) and (3) = ΔH° = +544.0 kJ + (-696.6 kJ)
= +544.0 kJ - 696.6 kJ)
= -152.6 kJ
Since the required reaction is (3) which is FeO(s) + Zn(s) → Fe(s) + ZnO(s)
we divide the enthalpy change for reaction (4) by 2 to obtain the enthalpy change for reaction (3).
So, ΔH° = -152.6 kJ/2 = -76.3 kJ
So, the standard enthalpy change for the reaction
FeO(s) + Zn(s) → Fe(s) + ZnO(s) is -76.3 kJ
What is Bose Einstein state of matter
Answers
Nitric acid and nitrogen monoxide react to form nitrogen dioxide and water, like this: At a certain temperature, a chemist finds that a 7.7 L reaction vessel containing a mixture of nitric acid, nitrogen monoxide, nitrogen dioxide, and water at equilibrium has the following composition: compound amount
HNO 16.2 g 11.0 g 18.6 g H20 236.7 g 3 NO NO
Calculate the value of the equilibrium constant K for this reaction. Round your answer to 2 significant digits.
Answers
Answer:
K = 3.3
Explanation:
Nitric acid, HNO3, reacts with nitrogen monoxide, NO, to produce nitrogen dioxide, NO2 and water H2O as follows:
2HNO3(g) + NO(g) → 3NO2(g) + H2O(g)
Where equilibrium constant, K, is:
K = [NO2]³[H2O] / [HNO3]²[NO]
[] is the molar concentration of each species at equilibrium.
To solve this question we need to find molarity of each gas and replace these in the equation as follows:
[NO2] -Molar mass NO2-46.0g/mol-
18.6g * (1mol/46.0g) = 0.404mol / 7.7L = 0.0525M
[H2O] -Molar mass:18.01g/mol-
236.7g * (1mol/18.01g) = 13.14 moles / 7.7L = 1.707M
[HNO3] -Molar mass:53.01g/mol-
16.2g * (1mol/53.01g) = 0.3056 moles / 7.7L = 0.0397M
[NO] -Molar mass: 30.0g/mol-
11.0g * (1mol/30.0g) = 0.367 moles / 7.7L = 0.0476M
Replacing:
K = [NO2]³[H2O] / [HNO3]²[NO]
K = [0.0525M]³[1.707M] / [0.0397M]²[0.0476M]
K = 3.3
Determine whether the statement about identifying a halide is true: Regardless of any concentration of ammonium solution, the precipitates in the reaction solution of my unknown halide after 0.1M AgNO3 remain because my unknown halide solution contains Br. Select one: True False
Answers
Answer:
False
Explanation:
The statement ; Regardless of any concentration of ammonium solution the precipitate of unknown halide after 0.1M AgNO3 will remain is FALSE
This is Because the remaining concentration of AgNO3 is dependent on the solubility of Ag⁺
A 18.0 L gas cylinder is filled with 6.20 moles of gas. The tank is stored at 33 ∘C . What is the pressure in the tank?
Express your answer to three significant figures and include the appropriate units.
Answers
Answer:
8.65 atm
Explanation:
Using ideal law equation;
PV = nRT
Where;
P = pressure (atm)
V = volume (L)
n = number of moles (mol)
R = gas law constant (Latm/molK)
T = temperature (K)
According to the information given in this question;
V = 18.0 L
n = 6.20 moles
R = 0.0821 Latm/molK
T = 33°C = 33 + 273 = 306K
P = ?
Using PV = nRT
P × 18 = 6.20 × 0.0821 × 306
18P = 155.76
P = 155.76/18
P = 8.65 atm
A reaction was performed, and the dichloromethane solvent was dried by adding magnesium sulfate drying agent. When the reaction flask was shaken, it was observed that the magnesium sulfate clumped together at the bottom of the flask. What does this observation indicate
Answers
The clumping of magnesium sulfate means that the wrong kind of drying agent have been used for the sample.
What is a drying agent?A drying agent is also referred to as a desiccant. It is a substance that is used to remove moisture from a sample. We must recall that the drying agent to be used must not react with the sample.
Since the magnesium sulfate was found to clump together at the bottom of the flask, it means that the wrong kind of drying agent have been used for the sample.
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what is the IUPAC name of 2NaOH(s)
Answers
Answer:
NaoH= sodium hydroxide
Suppose you are using distillation to separate cyclohexane and toluene. The boiling point of cyclohexane is Choose... oC and the boiling point of toluene is Choose... oC. Therefore, the liquid collected first should be Choose... .
Answers
Answer:
81°C
111°C
cyclohexane
Explanation:
Distillation is a process of separating two liquids based on differences in Bolling point. For two substances having different boiling points, they are collected as they are converted into vapour, condensed and move down the condenser one after the other.
Since the boiling point of cyclohexane is less than that of toluene, cyclohexane is collected first before toluene.
State whether the error introduced by each of the following problems would result in a high or a low value for the Cu recovery or would not affect the results. Explain. a. Some of the copper nitrate solution splashes out of the beaker in step 1. _____________
Answers
Answer:
Low value for copper recovery
Explanation:
The percentage recovery is obtained from;
Percent recovery = amount of substance you actually collected / amount of substance you were supposed to collect × 100
Note that the fact that some of the copper nitrate solution splashed out of the beaker means that some amount copper has been lost from the system. This loss of copper leads to a lower value of copper recovered from solution.
name a factor tht affects the value of electron affinity
Answers
Answer:
Atomic sizeNuclear chargesymmetry of the electronic configurationConsider the constitutional isomers 2-methylbut-1-ene, 2-methylbut-2-ene, and 3-methylbut-1-ene. When each of these alkenes is subjected to catalytic hydrogenation (H2, Pt), a single product results. Which of the following best describes the structural relationship among these products?
a. the product are cis-trans isomers.
b. the product are identical.
c. the product are constitutional isomers.
d. the product are enantiomers.
e. the product are diastereomers.
Answers
Answer:
Explanation:
I am almost sure that the products are identical.
What is the hydrogen atoms in 39.6g of ammonium sulphate,NH4 2SO4
Answers
14.45 x 10 23 atoms
……….is strong due to the ……………..between positive ions and negative delocalized electrons
Answers
Answer:
atom &bond
Explanation:
atom is strong due to the bond
A 70.0‑g piece of metal at 80.0 °C is placed in 100 g of water at 22.0 °C contained in a calorimeter. The metal and water come to the same temperature at 24.6 °C. How much heat did the metal give up to the water?
Answers
Answer:
1087.84 J
Explanation:
From the question given above, the following data were obtained:
Mass of metal (Mₘ) = 70 g
Temperature of metal (Tₘ) = 80 °C
Mass of water (Mᵥᵥ) = 100 g
Temperature of water (Tᵥᵥ) = 22 °C
Equilibrium temperature (Tₑ) = 24.6 °C
Heat lost by metal (Qₘ) =?
NOTE: Specific heat capacity of water (Cᵥᵥ) = 4.184 J/gºC
Heat lost by metal (Qₘ) = Heat gained by water (Qᵥᵥ)
Qₘ = Qᵥᵥ
Thus, we shall determine the heat gained by water. This can be obtained as follow:
Qᵥᵥ = MᵥᵥCᵥᵥ(Tₑ – Tᵥᵥ)
Qᵥᵥ = 100 × 4.184 (24.6 – 22)
Qᵥᵥ = 418.4 × 2.6
Qᵥᵥ = 1087.84 J
Thus, the heat gained by water is 1087.84 J.
Heat lost by metal (Qₘ) = Heat gained by water (Qᵥᵥ)
Qₘ = Qᵥᵥ
Qᵥᵥ = 1087.84 J
Qₘ = 1087.84 J
Therefore, the heat lost by the metal is 1087.84 J
A 70.0‑g piece of metal at 80.0 °C is placed in 100 g of water at 22.0 °C contained in a calorimeter. After reaching a temperature of 24.6 °C, the heat given up by the metal to the water is -1.08 kJ.
What is a calorimeter?A calorimeter is an object used for calorimetry, or the process of measuring the heat of chemical reactions or physical changes as well as heat capacity.
A 70.0‑g piece of metal at 80.0 °C is placed in 100 g of water at 22.0 °C contained in a calorimeter. The final temperature of the system is 24.6 °C.
Let's use the following expression to calculate the heat absorbed by the water.
Qw = c × m × ΔT
Qw = (4.184 J/g.°C) × 100 g × (24.6 °C - 22.0 °C) = 1.08 kJ
where,
Qw is the heat absorbed by the water.c is the specific heat capacity of water.m is the mass of water.ΔT is the change in the temperature for water.According to the law of conservation of energy, the sum of the heat absorbed by the water and the heat released by the metal (Qm) is zero.
Qw + Qm = 0
Qm = -Qw = -10.8 kJ
A 70.0‑g piece of metal at 80.0 °C is placed in 100 g of water at 22.0 °C contained in a calorimeter. After reaching a temperature of 24.6 °C, the heat given up by the metal to the water is -1.08 kJ.
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An antacid tablet weighing 1.30g was fully neutralized at 42.00 mL(an excess amount) of 0.250MHCl. 10.00 mL of 0.100 M NaOH was then used to back titrate the excess HCl. How many moles of acid did the antacid neutralize
Answers
Answer:
0.0095 moles of acid were neutralized by the antiacid
Explanation:
The antiacid is a base that neutralize the acid in stomach. To find the moles of acid neutralized we need to find the moles of acid added initially. This acid is added in excess, then, the moles of NaOH added reacts to neutralize the moles of acid in excess. The difference between initial moles of HCl and moles of NaOH needed to titrate the excess = Moles of HCl that were neturalized by the antiacid as follows:
Moles HCl added:
42.00mL = 0.04200L * (0.250mol/L) = 0.0105 moles HCl
Moles NaOH to titrate the excess:
10.00mL = 0.01000L * (0.10mol/L) = 0.0010 moles NaOH = Moles HCl in excess.
Moles of acid that were neutralized:
0.0105 moles - 0.0010 moles =
0.0095 moles of acid were neutralized by the antiacidHow is the compound NH3 classified?
A. As a salt
B. As a base
C. As an acid
D. As ionic
Answers
Answer:
B
Explanation:
Ammonia is considered a base as it's pH is 11
Answer from Gauthmath
The compound NH3 (Ammonia) can be classified as a weak Base. Below you can learn more about Ammonia.
What is Ammonia (NH3)?Ammonia is a chemical compound which is derived from the combination of Nitrogen and Hydrogen. It is denoted by the chemical formula NH3.
Ammonia is a base and when it reacts with acids to gives out salts. Physically, It is a colorless gas with a distinct characteristic of a pungent smell.
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