Pure acetic acid is often called glacial acetic acid because it is purified by fractional freezing at its melting point of 16.6 °C. At 1 atm, a flask containing several moles of acetic acid at 16.6 °C is briefly lowered into an infinitely large ice-water bath. When it is removed it is found that exactly 1 mol of acetic acid has frozen. Given: ΔH_fusion,acetic acid = 11.45kJ/mol and ΔH_fusion, H2O= 6.01 kJ/mol.

Required:
a. What is the change in entropy of the acetic acid?
b. What is the change in entropy of the water bath?
c. Now consider that the water bath and acetic acid are the same system. What is the entropy change for the combined system? Is the process reversible or irreversible? Why?

Answers

Answer 1

Answer:

Explanation:

a ) ΔH_fusion of acetic acid is 11.45 kJ / mol . It means 11.45 kJ of heat will be released when 1 mole of acetic acid will  freeze . During this process temperature of acetic acid will be constant .

Temperature of acetic acid  T = 16.6⁰C = 273 + 16.6 K = 289.6 K .

By definition change in entropy

ΔS = dQ / T

= dH / T

As temperature remains constant during withdrawal of heat

ΔS = ΔH / T

T = 289.6 K .

ΔH = - 11.45kJ

ΔS = - 11.45kJ / 289.6

= - 11450 / 289.6

= - 39.53 J

It will be negative as heat is released by acetic acid .

b )

Heat amounting ΔH will be absorbed by water bath so its entropy will be increased . As water bath is very large , temperature of bath also will remain constant at 289.6 K .

Increase in entropy of water bath =

ΔS = ΔH / T

T = 289.6 K .

ΔH =  11.45kJ

ΔS =  11.45kJ / 289.6

=  11450 / 289.6

=  39.53 J

c )

consider that the water bath and acetic acid are the same system : --

Total change in the heat content of the system

= 289.6 - 289.6 = 0

So for the whole system

ΔQ =ΔH = 0

Change in entropy is zero .

Δ G = ΔH - TΔS

= ΔH - ΔH = 0

ΔG = 0

Change in entropy is zero .


Related Questions

In a laboratory experiment, students synthesized a new compound and found that when grams of the compound were dissolved to make mL of a diethyl ether solution, the osmotic pressure generated was atm at K. The compound was also found to be nonvolatile and a non-electrolyte. What is the molar mass they determined for this compound

Answers

The question is incomplete, the complete question is;

In a laboratory experiment, students synthesized a new compound and found that when 12.23 grams of the compound were dissolved to make 228.1 mL of a benzene solution, the osmotic pressure generated was 4.55 atm at 298 K. The compound was also found to be non-volatile and a non-electrolyte. What is the molecular weight they determined for this compound?

Answer:

287.76 g/mol

Explanation:

From;

π = M R T

M = molarity

R= gas constant

T = temperature

number of moles = π * volume/RT

number of moles = 4.55 * 228.1/1000/0.082 * 298

number of moles = 1.037855/24.436

number of moles = 0.0425 moles

Molar mass = mass/number of moles

Molar mass = 12.23 grams/0.0425 moles

Molar mass = 287.76 g/mol

A student determines the chromium(III) content of a solution by first precipitating it as chromium(III) hydroxide, and then decomposing the hydroxide to chromium(III) oxide by heating. How many grams of chromium(III) oxide should the student obtain if her solution contains 56.0 mL of 0.600 M chromium(III) nitrate?

Answers

Answer:

Explanation:

Chromium nitrate Cr( NO₃ )₂

Chromium hydroxide Cr( OH)₃

Chromium oxide ( Cr₂O₃ )

1 mole of chromium nitrate will form 1 mole of chromium hydroxide

1 mole of chromium hydroxide will form one mole of chromium oxide .

Moles of chromium nitrate in 56 mL of .6 M solution

= .056 x .6 = .336 moles

.336 moles of chromium nitrate will produce .336 moles of chromium hydroxide and .336 moles of chromium hydroxide will produce .336 moles of chromium oxide .

So chromium oxide produced = .336 moles

Molecular weight of chromium oxide = 152

.336 moles of chromium oxide is equal to

.336 x 152 grams of chromium oxide

= 51.07 grams .

The value of the rate constant for a gas phase reaction can be changed by increasing the A. temperature of the reaction vessel. B. volume of the reaction vessel. C. pressure of the reactant. D. amount of product.

Answers

Answer:

temperature of the reaction vessel

Explanation:

temperature of the reaction vessel

The value of the rate constant for a gas phase chemical reaction can be changed by increasing the: A. temperature of the reaction vessel.

What is the rate constant?

In Chemistry, rate constant is typically used with rate law to tell the reaction rate or rate of a chemical reaction that is affected by activation energy.

The rate law equation.

Mathematically, the rate law is given by this formula:

[tex]R = k[A]^x[B]^y[/tex]

Where:

k is the rate constant.A is the concentration of reactant A.B is the concentration of reactant B.

Generally, the value of the rate constant for a gas phase chemical reaction can be changed by increasing the temperature of the vessel (container) that is used in conducting the chemical reaction.

Read more on rate constant here: brainly.com/question/24749252

Hurry I need Now!!!In which biome would the climax species be reached most quickly following a fire?
A Taiga
B desert
C Grassland
D. deciduous forest
E tropical rain forest

Answers

Answer:

D. Deciduous Forest.

Explanation:

How many atoms are in 0.580 moles of CO2?

Answers

Answer:

[tex]1.05x10^{24}atoms[/tex]

Explanation:

Hello!

In this case, according to the definition of the Avogadro's number, it is possible to realize that one molecule of CO2 contains 3 moles of atoms, one of carbon and two of oxygen, thus, we have:

[tex]0.580molCO_2*\frac{3mol\ atoms}{1molCO_2} =1.74mol\ atoms[/tex]

Then, we use the Avogadro's number to obtain:

[tex]1.74mol\ atoms*\frac{6.022x10^{23}atoms}{1mol\ atoms} \\\\1.05x10^{24}atoms[/tex]

Best regards!

What is the mass in grams of 2.5 mol of O2?

Answers

Answer:

80grams

Explanation:

RAM of O=16

molar mass of O2= 16×2=32g/mol

mass= mole × molar mass

= 2.5×32= 80g

Identify the chromatography term that corresponds to each definition.
A value that quantifies the distance traveled by a substance relative to the distance traveled by the solvent Choose...
A method used to separate components of a mixture Choose...
The substance to which the sample is bound at the start of an experiment Choose...
The substance that carries the components of a mixture Choose...

Answers

Answer:

A value that quantifies the distance traveled by a substance relative to the distance traveled by the solvent- Retention factor

The substance to which the sample is bound at the start of an experiment- stationary phase

The substance that carries the components of a mixture- mobile phase

Explanation:

The retention is defined as a value that quantifies the distance traveled by a substance relative to the distance traveled by the solvent. It shows us how effective a solvent is at separating a mixture.

The stationary phase is the the substance to which the sample is bound at the start of an experiment. The solvent pick up the substance to be analyzed from this stationary phase. The different components of the mixture are found to move up the stationary phase at different speeds, causing them to eventually  separate from each other.

The mobile phase is the substance that carries the components of a mixture during chromatography.

What is a personal factor of resilience?

A. Feeling of belonging

B. Family and friends

C. Genetics

D. Coping Mechanisms

Answers

Answer:

B

Explanation:

B is a personal factor of resilience

Please help

15 points

Answers

Further explanation

Given

Atomic symbol

Required

Atomic composition

Solution

Atomic number = number of protons = number of electrons

Mass Number (A) is the sum of protons and neutrons

Number of protons and Number of Neutrons  in nucleus

Number of electrons in the shell

From the picture:

protons = 3

neutrons = 4

electrons = 3

atomic number = protons = electrons = 3

mass number = protons + neutrons = 3+4 = 7

Why is the liquid oxygen machine producing less liquid oxygen than normal?

Answers

Answer:

Liquid oxygen evaporates at only a slightly higher temperature than liquid nitrogen because they have similarly low attraction between molecules. This would mean less liquid oxygen is coming out of tank 3 because some of it is evaporating as a gas instead.

The liquid oxygen machine is producing less liquid oxygen than normal because there's a low attraction between the molecules.

It should be noted that oxygen in its liquid state will take up less space. It can also be stored at a lower pressure than when it's in its gaseous state.

From the complete question, the liquid oxygen evaporates at a slightly higher temperature than the liquid nitrogen. The reason for this is due to the fact that they have similarly low attraction between molecules.

Read related link on:

https://brainly.com/question/16173485

Energy can generally be considered to be either kinetic energy or potential energy. Some specific forms of energy, such as
electrical, magnetic, and gravitational energy, can operate in the space around objects and affect other objects that come near. In
these examples
A. energy is continuously created.
B. energy is continuously destroyed.
C. energy exists in a field.
D. all of these

Answers

Answer:

d hope it's right hope this helps

Answer:

Energy exists in a field.

Explanation:

Electrical field, magnetic field, and gravitational field.

A and B are wrong otherwise the law of conservation of energy would be violated

what the the noble gas configuration for Boron

Answers

Answer:

[He]2[tex]s^{2}[/tex]3[tex]p^{1}[/tex]

Explanation:

The electron configuration for Boron is 1[tex]s^{2}[/tex]2[tex]s^{2}[/tex]3[tex]p^{1}[/tex], but you can also write it as the noble gas configuration, which is [He]2[tex]s^{2}[/tex]3[tex]p^{1}[/tex]

Note that helium has the configuration of 1[tex]s^{2}[/tex], so we instead of writing it, we write [He]. This can be useful when writing the configurations of elements from the later periods as it saves space.

Answer:-
Dude............G00gle the configuration

what is 78%
of 100? help​

Answers

78. Any percent of 100 is literally the number just wi th out the percent. Like 38 percent of 100 is 38. PLEASE MARK BRAINLIEST

Answer:

78

Explanation:

You have 100%, you take 22% and get 78%

50 points Two waves combine with constructive interference. What must be true of the
combined wave that forms?
A. It has a lower frequency than that of the original waves.
B. It has a higher amplitude than that of the original waves.
C. It has a higher frequency than that of the original waves.
D. It has a lower amplitude than that of the original waves.

Answers

Answer:B

Explanation:

Maybe

Answer:B is correct

Explanation:

235U92 + 1N0 + 135Cs55 + 99Rb37 + x1n0

Answers

Es hora de comár. Es hora de comár :)

What type of equation is this?
AlCl3 + NaOH → Al(OH)3 + NaCL
double
single
synthesis
decomp
combustion

Answers

Double. I guess, I’m sorry.

metric conversion ( convert )

Answers

Answer:

13. 2g

14. 5000mL

15. 104,000m

16. 160mm

17. 5600000mg

18. 10hs

19. 0.250km

20. 1daL

Explanation:

13. 1000milligram (mg) = 1gram (g)

Hence, 2000mg = 2000/1000

= 2g

14. 1 litre (L) = 1000millilitre (mL)

Hence, 5L = 5 × 1000

= 5000mL.

15. 1kilometre (km) = 1000metre (m)

Hence, 104km = 104 × 1000

= 104,000m

16. 1 centimetre (cm) = 10millimeters (mm)

Hence, 16cm = 16 × 10

= 160mm

17. 1kilogram (kg) = 1000000 milligram (mg)

Hence, 5.6kg = 5.6 × 1000000

= 5600000mg

18. 1 second (s) = 0.01 hectosecond (hs)

Hence, 1000s = 1000 × 0.01

= 10hs

19. 1000metre (m) = 1kilometre (km)

Hence, 250m = 250/1000

= 0.250km

20. 1 centiliter (cl) = 0.001 Decaliter (daL)

Hence, 1000cl = 1000 × 0.001

= 1daL

13) How many moles of CH3NH2 can be produced
from 24 moles of N2?

Answers

Answer:

To answer this question we would need the Molecular empirical formula that relates the reactant of N2 to the final product of CH3NH2. Then it would be easily solved by using stoichiometric ratios. Basically it is done similar to unit conversion problems.

Helppp plssss pls help it’s Science I will give Brainlyist no cap I will just plssss help

Answers

Answer:

I cant see it that well but id be happy to help if u post a clearer picture!

Explanation:

show the formation of Mgion and Oion.

Answers


Cation present in MgO→Mg
2+


Anion present in MgO→O
2−

Answer and I’ll give you brainliest!
What type of reaction is this *
N2 + H2 → NH3
O synthesis
O combustion
O decomp
O single
O double

Answers

Combustion. As they are heated at extreme temperatures to form ammonia through Haber process

What is the mass of 5 liters of fluorine (F2) gas at STP?

Answers

Answer:

The molar density of any ideal gas at STP is:

1 mol / 22.4 L = 0.04464 mol / L

The molar mass of F2 is: 2(19) = 38 g/mol

0.04464 mol / L * (38 g / mol) = 1.70 g/L

Explanation:

How many moles are in 3.69 x 1022 atoms of Ag?​

Answers

Answer:

I'm assuming that 1022 is supposed to be 10^22, or 10 to the 22nd power. If that is the case, then the answer is 0.0612956811 mol. Round it to the number that you are supposed to round it to.

Help pls!!!!!!!!!!!!!!!!!!!!!!!

Answers

Answer:

D a compound

Explanation:

D.
it is a compound and D is the right answer

Why is HCI a strong acid and HCIO a weak acid?

Answers

Strong Acid: dissolves and dissociates 100% to produce protons (H+) 1. seven strong acids: HCl, HBr, HI, HNO3, H2SO4, HClO4, & HClO3 2. ... Weak Acid: dissolves but less than 100% dissociates to produce protons (H+) 1.

PLEASE HELP it’s due in 30 minutes

Answers

Answer:

1-6

3 1 3 3 2 2

Explanation:

Which of the following notations represents an alpha particle?
A. 2 He
C.B+
В. В
D. Y

Answers

Answer:

A. 2 He

Explanation:

The notation of an alpha particle is depicted as:

                     ₂He

An alpha particles is a nucleus of 2 protons and 2 neutrons. So it is actually a Helium cation.

Alpha particles are monoenergetic and they mostly have discrete energy.

So, the mass number of the particle is 4 and atomic number is 2

If you travel through a city and find that you travel 5 km in 30 minutes, you could say that your constant speed is 6 km/h. is it true of false

Answers

Answer:

False.

Explanation:

(5 kilometers / 30 minutes), you could then say that in 60 minutes (one hour) you would be traveling at (10 kilometers / 60 minutes)...

Therefore, it is unlikely that you would be traveling at (6 kilometers / hour), so the answer should be... False.

Carbon monoxide and carbon dioxide have

Answers

Answer:

different chemical properties and the same physical properties

Explanation:

Both carbon monoxide and carbon dioxide are gases.

So physically, the two compounds have no fixed shape and volume and their molecules are far apart.

Therefore, they have similar physical properties.

Based on chemical properties, the compounds or molecules given are different.

They will combine chemically in diverse ways.

3. different chemical properties and the same physical properties

Physical properties:  

Both carbon monoxide and carbon dioxide are gases. So physically, the two compounds have no fixed shape and volume and their molecules are far apart.  Therefore, they have similar physical properties.

Chemical properties:

The compounds or molecules given are different.  They will combine chemically in diverse ways.Carbon Dioxide (CO₂) is a chemical compound consisting of one carbon atom and two oxygen atoms while Carbon Monoxide (CO) is a chemical compound which contains one carbon atom and one oxygen atom.CO is also a colorless and odorless gas while CO₂ is entirely human-made and is not naturally present in the atmosphere.Thus, both gases are chemically different.

Therefore, option 3 is correct.

Learn more:

brainly.com/question/15821287

A sample of compound A (a clear, colorless gas) is analyzed and found to contain 4.27g carbon and 5.69g oxygen. A sample of compound B (also a clear, colorless gas) is analyzed and found to contain 5.19g carbon and 13.84g oxygen. Are these data an example of the law of definite proportions, the law of multiple proportions, or neither? What do these data tell you about substances A and B?

Answers

Answer:

law of multiple proportions

Explanation:

The law of multiple proportions states that, if two elements A and B, combine to form more than one chemical compound. Then the various masses of one element A, which combine separately with a fixed mass of element B are in  simple multiple ratio.

We can see that the ratio of oxygen that combines with carbon in the two compounds( A and B) is 1:2. This demonstrates the law of multiple proportions.

The substances A and B must be CO and CO2 respectively.

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