An aqueous solution contains 0.374 M ammonia (NH3). How many mL of 0.276 M nitric acid would have to be added to 125 mL of this solution in order to prepare a buffer with a pH of 8.970.

Answers

Answer 1

Answer:

111.95mL of HNO3 are needed to prepare the buffer

Explanation:

We can solve this equation using H-H equation for bases:

pOH = pKb + log [HA+] / [A]

Where pOH is the pOH of the solution

pOH = 14 - pH = 14 - 8.970 = 5.03

pKb is the pKb of NH3 = 4.74

[HA+] could be taken as moles of NH4+

[A] as moles of NH3

The NH3 reacts with nitric acid, HNO3, as follows:

NH3 + HNO3 → NH4+ + NO3-

That means the moles of HNO3 added = X = Moles of NH4+ produced

And moles of NH3 are initial moles NH3 - X

Initial moles of NH3 are:

0.125L * (0.374mol/L) = 0.04675 moles NH3

Replacing in H-H equation:

pOH = pKb + log [HA+] / [A]

5.03 = 4.74 + log [X] / [0.04675-X]

0.29 = log [X] / [0.04675-X]

1.95 =  [X] / [0.04675-X]

0.0912 - 1.95X = X

0.0912 = 2.95X

X = 0.0309 moles

We need to add 0.0309 moles of HNO3. From a solution that is 0.276M:

0.0309 moles of HNO3 * (1L / 0.276moles) = 0.11195L of HNO3 are needed

In mL:

111.95mL of HNO3 are needed to prepare the buffer


Related Questions

What does quantization refer to?

Answers

Answer:

Quantization is the process of constraining an input from a continuous or otherwise large set of values (such as the real numbers) to a discrete set (such as the integers).

Explanation:

Quantization refers to the situation where an electromagnetic field consists of discrete energy parcels, photons.

What is Quantatization in Chemistry ?

In Chemistry , the concept that a system cannot have any possible energy value but instead is limited to certain specific energy values (states). This states depend on the specific system in question.

Under this system, Energy could be gained or lost only in integral multiples of some smallest unit of energy, a quantum (the smallest possible unit of energy).

Hence, Quantization refers to the situation where an electromagnetic field consists of discrete energy parcels, photons.

Learn more about Quantum here ;

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Phosphorylation of enzymes:_______.
a. always increases their activity.
b. generally occurs on Ser, Thr, and/or Tyr side chains and to a lesser extent on the His side chain.
c. is irreversible.
d. is one of only five known covalent forms of regulation.

Answers

Answer:

generally occurs on Ser, Thr, and/or Tyr side chains and to a lesser extent on the His side chain

Protons,neutrons and electrons are not considered as------------ *

Answers

Electrons are a type of subatomic particle with a negative charge. Protons are a type of subatomic particle with a positive charge. ... Neutrons are a type of subatomic particle with no charge (they are neutral). Like protons, neutrons are bound into the atom's nucleus as a result of the strong nuclear force.

Five kg of carbon dioxide (CO2) gas undergoes a process in a well-insulated piston-cylinder assembly from 2 bar, 280 K to 20 bar, 520 K. If the carbon dioxide behaves as an ideal gas, determine the amount of entropy produced, in kJ/K.

Answers

This question is incomplete, the complete question is;

Five kg of carbon dioxide (CO2) gas undergoes a process in a well-insulated piston-cylinder assembly from 2 bar, 280 K to 20 bar, 520 K. If the carbon dioxide behaves as an ideal gas, determine the amount of entropy produced, in kJ/K. Assuming;

a) constant specific heats Cp = 0.939 kJ/Kg K

b) variable specific heats

Answer:

a) the amount of entropy produced is 0.731599 kJ/K

b) the amount of entropy produced is 0.69845 kJ/K

Explanation:

Given the data in the question;

5 kg of carbon dioxide (CO₂) gas undergoes a process in a well-insulated piston-cylinder assembly.

m = 5 kg

Molar mass M = 44.01 g/mol

P₁ = 2 bar, P₂ = 20

T₁ = 280 K, P₂ = 520 K

Since its insulated { q = 0 } ( kinetic and potential energy effects = 0 )

Now,

a) the amount of entropy produced, in kJ/K, Assuming constant specific heats with Cp = 0.939 kJ/Kg K

S[tex]_{Generation[/tex] = m × ((Cp × In( T₂/T₁) - R × In( P₂/p₁ ))

we substitute

S[tex]_{Generation[/tex] = 5 × (( 0.939  × In( 520/280) - 0.1889 × In( 20/2 ))

= 5 × ( 0.5812778 - 0.434958 )

= 5 × 0.1463198

= 0.731599 kJ/K

Therefore, the amount of entropy produced is 0.731599 kJ/K

b) the amount of entropy produced, in kJ/K, Assuming variable specific heats.

Now, from  Table A-23: Ideal Gas Properties of Selected Gases;

T₁,T₂ : s₁⁰ = 211.376 kJ/kmol-K, s₂⁰ = 236.575 kJ/kmol-K

now, s₁ = s₁⁰ / M and s₂ = s₂⁰ / M

we substitute

s₁ = s₁⁰ / M = 211.376 / 44.01  = 4.8029 kJ/kg

s₂ = s₂⁰ / M = 236.575 / 44.01 = 5.37548 kJ/kg

S[tex]_{Generation[/tex] = m × (( s₂ - s₁ ) - R × In( p₂ / p₁ ))

we substitute

S[tex]_{Generation[/tex] = 5 × (( 5.37548 - 4.8029  ) - 0.1880 × In( 20 / 2 ))

= 5 × ( 0.57258 - 0.432885997 )

= 5 × 0.13969

= 0.69845 kJ/K

Therefore, the amount of entropy produced is 0.69845 kJ/K

what is the difference between red phosphorus and white phosphorus?​

Answers

Answer:

White phosphorusRed PhosphorusIt is insoluble in water but soluble in carbon disulphide.It is insoluble in both water and carbon disulphide.It undergoes spontaneous combustion in air.It is relatively

Explanation:

I hope it will help you

g consider the following pair of aqueous solutions. which pair will result in the formation of a precipitate? give the formula for the precipitate in the blank. write none if no precipitate forms. a) libr and nh4no3 b) kcl and pb(ch3coo)2

Answers

Answer:

kcl and pb(ch3coo)2

The precipitate is PbCl2

Explanation:

Let us take the options provided one after the other;

In the first case, we have;

LiBr(aq) + NH4NO3(aq) ----> LiNO3(aq) + NH4Br(aq)

You can see that no precipitate is formed here.

In the second case;

2KCl(aq) + Pb(CH3COO)2(aq) ----> PbCl2(s) + 2CH3COOK(aq)

The precipitate here is PbCl2.




Read the scales of this balance.
The unknown sample has a mass of:
11.2 g
01.012 kg
1.220 g
O 1.200 g

Answers

Answer:

and I'll call you when the party's over

quiet when I'm come in home

when I'm all alone

Answer:

Explanation:

Don't you know too much already?

I'll only hurt you if you let me

Call me friend but keep me closer (call me back)

And I'll call you when the party's over

Critique this statement: Promotion of electrons is accompanied by a release of energy

Answers

Answer: Promotion of electrons is accompanied by a release of energy because of absorption of photon.

Explanation:

Promotion of electrons occurs when an electron accepts or absorbs a photon which leads to it's movement from a lower energy level orbital to a higher energy orbital.

According to Bohr, the electrons was restricted to certain energy levels and was thought to move along certain circular orbits around the nucleus. These energy levels were identified by means of principal quantum number, n. The wave mechanics model of atom does not restrict the electrons to a certain energy levels only. Instead it describes a region around the Nucleus called orbitals where there is a possibility of finding an electron with a certain amount of ENERGY.

The energy levels are composed of one or more orbitals and the distribution of electrons around the nucleus is determined by the number and kind of energy levels that are occupied.

Bohr made an assumption that an electron emits energy in the form of radiation when it moves from a higher to a lower permitted orbit, this produces a line in the atomic emission spectrum. Since the energies of the higher and lower orbits are fixed, the line will be of a particular energy and frequency.

What is a reaction rate?

Answers

Answer:

A reaction is the time that is required for a chemical reaction to go essential to completion

Help me with these please

Answers

Answer:

Help you with what hmm I do not know what you are talking about

What process occurs during the corrosion of iron?
Answers

A.
Iron is oxidized.

B.
Iron is reduced.

C.
Iron (III) is oxidized.

D.
Iron (III) is reduced.

Answers

Answer:

A

Explanation:

The iron corrodes so it oxidized

What volume of each solution contains 0.14 mol of KCl? Express your answer using two significant figures.

1.8 M KCl

Answers

Answer:

Solution given:

1 mole of KCl[tex]\rightarrow [/tex]22.4l

1 mole of KCl[tex]\rightarrow [/tex]74.55g

we have

0.14 mole of KCl[tex]\rightarrow [/tex]74.55*0.14=10.347g

74.55g of KCl[tex]\rightarrow [/tex]22.4l

10.347 g of KCl[tex]\rightarrow [/tex]22.4/74.55*10.347=3.11litre

volume of each solution contains 0.14 mol of KCl contain 3.11litre.

1 mol of any gas contains 22.4L of volume at STP

Moles of KCl=0.14

Volume of KCl:-

0.14(22.4)3.14L

what gasous product would you expect when water is drop over calcium carbide​

Answers

Answer:

Ethyn gas ( acetylene gas )

Explanation:

All group II carbides react with water to form ethyn gas apart from beryllium which produces methane gas.

[tex]{ \sf{CaC_{2(s)} + 2H _{2} O_{(l)} → Ca(OH) _{2(s)} + C _{2} H _{2(g)} }}[/tex]

All of the following are TRUE for activities and activity coefficients, except: A) activity for a chemical species is the product of concentration and activity coefficient. B) the activity coefficient corrects for non-ideal behavior due to ionic strength. C) as ionic strength increases, the value of the activity coefficient increases. D) for ions, the activity coefficient approaches unity as the ionic strength approaches 0. E) the activity coefficient for neutral molecules is approximately unity.

Answers

Answer:

C) as ionic strength increases, the value of the activity coefficient increases.

Explanation:

The effective concentration of ions available for reactions is known as the activity of the ion.

The activity coefficient important in chemistry because it accounts for the deviation of a solution from ideal behaviour.

The activity of a chemical species is defines as the product of concentration and activity coefficient.

Following the Debye–Hückel limiting law; log γ = −0.509z2I1/2. The ionic strength of a solution tends to increase as the activity coefficient (γ) of the ion decreases.

0.5008 g of an unknown triprotic acid, H3A, is dissolved in 47.3 mL of water and then titrated with 0.315 M NaOH. It takes 25.72 mL of the NaOH solution to completely neutralize the acid. What is the molar mass of this acid

Answers

Answer:

The molar mass is "185.44 g/mol".

Explanation:

According to the question,

The moles of NaOH will be:

= [tex]\frac{0.315}{1000}\times 25.72[/tex]

= [tex]8.1018\times 10^{-3} \ moles[/tex]

Number of moles of an acid will be:

= [tex]\frac{8.1018\times 10^{-3}}{3}[/tex]

= [tex]2.7006\times 10^{-3} \ moles[/tex]

We know that,

⇒ [tex]Moles = \frac{Mass}{Molar \ mass}[/tex]

hence,

Molar mass of unknown acid will be:

= [tex]\frac{Mass \ in \ g}{Moles}[/tex]

= [tex]\frac{0.5008}{2.7006\times 10^{-3}}[/tex]

= [tex]185.44 \ g/mol[/tex]

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